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Oxidative Nitration of Alkenes with tert ‐Butyl Nitrite and Oxygen
Author(s) -
Taniguchi Tsuyoshi,
Yajima Atsushi,
Ishibashi Hiroyuki
Publication year - 2011
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201100315
Subject(s) - nitration , chemistry , nitrite , reagent , nitro , oxidative phosphorylation , nitrate , organic chemistry , oxygen , combinatorial chemistry , biochemistry , alkyl
A method for the oxidative nitration of alkenes using a combination of tert ‐butyl nitrite and molecular oxygen to give β‐nitro alcohols and their nitrate derivatives has been developed. The present reaction provides a practical method for the synthesis of nitro compounds because of the mild reaction conditions, the use of inexpensive reagents and a simple experimental procedure.
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