One‐Pot Ring‐Closing Metathesis (RCM)/Oxidation by an Assisted Tandem Ruthenium Catalysis for the Synthesis of 2‐Quinolones | Zendy

Kato Hiroshige | Zendy; Ishigame Tatsuya | Zendy; Oshima Nobuhiro | Zendy; Hoshiya Naoyuki | Zendy; Shimawaki Ken | Zendy; Arisawa Mitsuhiro | Zendy; Shuto Satoshi | Zendy

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One‐Pot Ring‐Closing Metathesis (RCM)/Oxidation by an Assisted Tandem Ruthenium Catalysis for the Synthesis of 2‐Quinolones

Author(s) -

Kato Hiroshige,

Ishigame Tatsuya,

Oshima Nobuhiro,

Hoshiya Naoyuki,

Shimawaki Ken,

Arisawa Mitsuhiro,

Shuto Satoshi

Publication year - 2011

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201100303

Subject(s) - ruthenium , chemistry , carbene , ring closing metathesis , metathesis , catalysis , tandem , combinatorial chemistry , salt metathesis reaction , methylene , organic chemistry , polymer , materials science , composite material , polymerization

We have developed a one‐pot ring‐closing metathesis (RCM)/oxidation methodology to yield various 2‐quinolines from 2‐vinyl‐ N ‐allylaniline derivatives. This is a first example of an oxidation involving methylene (CH 2 ) groups with modified Grubbs‐type ruthenium complexes. Hence, this adds an example of a non‐methathesis reaction using a ruthenium carbene catalyst.

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