Silver‐Catalyzed  exo ‐ dig ‐Azacyclization/[3+2] Cycloaddition Cascades on 1‐Tosylhydrazon‐4‐oxy‐5‐yne Substrates: Applicability to Diverse Alkenes | Zendy

Huple Deepak B. | Zendy; Chen ChunHao | Zendy; Das Arindam | Zendy; Liu RaiShung | Zendy

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Silver‐Catalyzed exo ‐ dig ‐Azacyclization/[3+2] Cycloaddition Cascades on 1‐Tosylhydrazon‐4‐oxy‐5‐yne Substrates: Applicability to Diverse Alkenes

Author(s) -

Huple Deepak B.,

Chen ChunHao,

Das Arindam,

Liu RaiShung

Publication year - 2011

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201100263

Subject(s) - chemistry , cycloaddition , catalysis , cascade reaction , dig , tandem , cascade , combinatorial chemistry , scope (computer science) , organic chemistry , programming language , chromatography , computer science , composite material , computer security , materials science

We report the silver‐catalyzed tandem 6‐ exo‐dig ‐azacyclization/[3+2] cycloaddition cascade on 1‐tosylhydrazon‐4‐oxy‐5‐ynes to form complicated azacyclic products regioselectively and efficiently. The new azacyclic syntheses have a wide range of reaction scope, with respect to both substrates and alkenes.

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