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Ligand‐Free Reusable Palladium‐Catalyzed Heck‐Type Coupling Reactions of Hypervalent Iodine Reagents under Mild Conditions
Author(s) -
Qu Xiaoming,
Sun Peng,
Li Tingyi,
Mao Jincheng
Publication year - 2011
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201100008
Subject(s) - hypervalent molecule , chemistry , palladium , reagent , catalysis , heck reaction , ligand (biochemistry) , iodine , combinatorial chemistry , coupling reaction , organic chemistry , biochemistry , receptor
Highly effective palladium‐catalyzed Heck‐type couplings of hypervalent iodine reagents are reported for the first time. It is noteworthy that such reactions could be carried out in the absence of ligand at 40 °C and the catalytic system could be easily reused for five times.