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The Actual Active Species of Sulfur‐Modified Gold‐Supported Palladium as a Highly Effective Palladium Reservoir in the Suzuki–Miyaura Coupling
Author(s) -
Hoshiya Naoyuki,
Shuto Satoshi,
Arisawa Mitsuhiro
Publication year - 2011
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201000820
Subject(s) - palladium , chemistry , sulfur , coupling (piping) , suzuki reaction , combinatorial chemistry , organic chemistry , catalysis , metallurgy , materials science
The actual active species of the recently developed sulfur‐modified, gold‐supported palladium material, S ‐modified A u‐supported Pd (SAPd), with one of the lowest Pd‐releasing levels and high recyclability in the Suzuki–Miyaura coupling, was investigated. Also, SAPd was found to work repeatedly as an excellent Pd reservoir for liquid‐phase combinatorial synthesis.