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Intermolecular Regioselective 1,2‐Diamination of Allylic Ethers
Author(s) -
Muñiz Kilian,
Kirsch Jonathan,
Chávez Patricia
Publication year - 2011
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201000813
Subject(s) - regioselectivity , chemistry , intermolecular force , allylic rearrangement , catalysis , palladium , amination , homogeneous , combinatorial chemistry , organic chemistry , molecule , physics , thermodynamics
Homogeneous palladium catalysis enables a novel intermolecular regioselective diamination of allylic ethers, which offers a convenient entry into 1,2,3‐trisubstituted products. These represent suitable building blocks with differently protected nitrogen atoms for subsequent synthetic application.