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Rhodium‐Catalysed Alkoxycarbonylative Cyclisation Reactions of 1,6‐Enynes
Author(s) -
Ziyanak Fırat,
Kuş Melih,
Artok Levent
Publication year - 2011
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201000772
Subject(s) - chemistry , rhodium , catalysis , medicinal chemistry , organic chemistry
Abstract The rhodium‐catalysed carbonylation of 1,6‐enynes possessing an electron‐deficient alkenyl moiety in an alcohol reagent in the presence of a rhodium complex proceeded stereo‐ and chemoselectively to afford exocyclic α,β‐enoates.