Base‐Mediated Tandem Reaction Consisting of an Acyl Shift Strategy Leading to 4,5‐Disubstiuted Furan‐2(5 H )‐ones | Zendy

Lei Yong | Zendy; Wang ZhiQiang | Zendy; Xie YeXiang | Zendy; Yu ShangCi | Zendy; Tang BoXiao | Zendy; Li JinHeng | Zendy

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Base‐Mediated Tandem Reaction Consisting of an Acyl Shift Strategy Leading to 4,5‐Disubstiuted Furan‐2(5 H )‐ones

Author(s) -

Lei Yong,

Wang ZhiQiang,

Xie YeXiang,

Yu ShangCi,

Tang BoXiao,

Li JinHeng

Publication year - 2011

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201000762

Subject(s) - chemistry , decarbonylation , tandem , furan , base (topology) , cascade reaction , stereochemistry , catalysis , organic chemistry , mathematical analysis , materials science , mathematics , composite material

The first example of the synthesis of 4,5‐disubstiuted furan‐2(5 H )‐ones by base‐mediated tandem acyl shift/cyclization/decarbonylation reactions of aroylmethyl 2‐alkynoates has been developed. This new and inexpensive tandem route allows both a CO bond and a C sp 3 C sp 2 bond forming in one step involving an unprecedented acyl rearrangement process.

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