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Iridium‐Catalyzed Enantioselective Hydrogenation of Cyclic Imines
Author(s) -
Chang Mingxin,
Li Wei,
Hou Guohua,
Zhang Xumu
Publication year - 2010
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201000473
Subject(s) - enantioselective synthesis , chemistry , iridium , catalysis , reactivity (psychology) , ligand (biochemistry) , ferrocene , cyclooctadiene , medicinal chemistry , asymmetric hydrogenation , organic chemistry , electrochemistry , medicine , biochemistry , alternative medicine , receptor , electrode , pathology
A catalytic complex made from [Ir(COD)Cl] 2 [di‐μ‐chloro‐bis(1,5‐cyclooctadiene)diiridium(I)] precursor and ( S,S )‐f‐Binaphane (( R , R )‐1,1′‐bis{( R )‐4,5‐dihydro‐3 H ‐dinaphtho[1,2‐ c :2′,1′‐ e ]phosphepino}ferrocene) ligand effectively catalyzed the enantioselective hydrogenation of cyclic imines with high reactivity and good enantioselectivity.