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A Mild Catalytic Oxidation System: Ruthenium Porphyrin and 2,6‐Dichloropyridine N ‐Oxide Applied for Alkene Dihydroxylation
Author(s) -
Hu WenXiang,
Li PeiRong,
Jiang Gaoxi,
Che ChiMing,
Chen Jian
Publication year - 2010
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201000455
Subject(s) - chemistry , dihydroxylation , porphyrin , alkene , ruthenium , catalysis , medicinal chemistry , oxide , organic chemistry , ruthenium oxide , combinatorial chemistry , enantioselective synthesis
A new method was developed to transform alkenes into three types of functional molecules, including epoxides, aldehydes and 1,2‐diols by using dichlororuthenium(IV) meso ‐tetrakis(2,6‐dichlorophenyl)porphyrin [Ru(IV)(TDCPP)Cl 2 ] as catalyst and 2,6‐dichloropyridine N ‐oxide (Cl 2 pyNO) as the oxidant, in which the 1,2‐diols were afforded via “one‐pot” reactions in moderate yields.