A Mild Catalytic Oxidation System: Ruthenium Porphyrin and 2,6‐Dichloropyridine  N ‐Oxide Applied for Alkene Dihydroxylation | Zendy

Hu WenXiang | Zendy; Li PeiRong | Zendy; Jiang Gaoxi | Zendy; Che ChiMing | Zendy; Chen Jian | Zendy

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A Mild Catalytic Oxidation System: Ruthenium Porphyrin and 2,6‐Dichloropyridine N ‐Oxide Applied for Alkene Dihydroxylation

Author(s) -

Hu WenXiang,

Li PeiRong,

Jiang Gaoxi,

Che ChiMing,

Chen Jian

Publication year - 2010

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201000455

Subject(s) - chemistry , dihydroxylation , porphyrin , alkene , ruthenium , catalysis , medicinal chemistry , oxide , organic chemistry , ruthenium oxide , combinatorial chemistry , enantioselective synthesis

A new method was developed to transform alkenes into three types of functional molecules, including epoxides, aldehydes and 1,2‐diols by using dichlororuthenium(IV) meso ‐tetrakis(2,6‐dichlorophenyl)porphyrin [Ru(IV)(TDCPP)Cl 2 ] as catalyst and 2,6‐dichloropyridine N ‐oxide (Cl 2 pyNO) as the oxidant, in which the 1,2‐diols were afforded via “one‐pot” reactions in moderate yields.

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