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Enantioselective Organocatalytic Rearrangement of α‐Acyloxy‐ β‐keto Sulfides to α‐Acyloxy Thioesters
Author(s) -
Capitta Francesca,
Frongia Angelo,
Piras Pier Paolo,
Pitzanti Patrizia,
Secci Francesco
Publication year - 2010
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201000376
Subject(s) - chemistry , enantioselective synthesis , yield (engineering) , organocatalysis , organic chemistry , catalysis , combinatorial chemistry , materials science , metallurgy
The first highly enantioselective organocatalytic rearrangement of α‐acyloxy‐β‐keto sulfides to α‐acyloxy thioesters has been developed which provides a number of important synthetic building blocks in high yield and with excellent enantioselectivities ( ee : up to 92%).