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Gold‐Catalyzed Synthesis of Bicyclo[3.2.0]heptenes via a Formal [3+2]/[2+2]‐Annulation of Allylsilane with 4‐Methoxybut‐2‐yn‐1‐ols
Author(s) -
Yang ChunYao,
Wang ChiouDong,
Tian ShuFan,
Liu RaiShung
Publication year - 2010
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201000201
Subject(s) - annulation , chemistry , bicyclic molecule , heptene , catalysis , stereochemistry , combinatorial chemistry , medicinal chemistry , organic chemistry
This work reports the novel gold‐catalyzed [3+2]/[2+2]‐annulation of allylsilane with 4‐methoxybut‐2‐yn‐1‐ols that yields highly strained bicyclo[3.2.0]heptene products efficiently and stereoselectively.