Enantioselective Carbonyl‐Ene Reactions of Trifluoropyruvate in Ionic Liquid  via  a Recyclable Indium(III)‐Pybox Complex | Zendy

Zhao Jun Feng | Zendy; Tan Boon Hong | Zendy; Zhu Ming Kui | Zendy; Tjan Teguh Budiono W. | Zendy; Loh Teck Peng | Zendy

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Enantioselective Carbonyl‐Ene Reactions of Trifluoropyruvate in Ionic Liquid via a Recyclable Indium(III)‐Pybox Complex

Author(s) -

Zhao Jun Feng,

Tan Boon Hong,

Zhu Ming Kui,

Tjan Teguh Budiono W.,

Loh Teck Peng

Publication year - 2010

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201000170

Subject(s) - enantioselective synthesis , chemistry , ionic liquid , indium , trifluoromethyl , catalysis , ene reaction , organic chemistry , medicinal chemistry , alkyl

A highly enantioselective carbonyl‐ene reaction of trifluoropyruvate catalyzed by a recyclable indium(III)‐pybox complex in ionic liquid afforded trifluoromethyl‐containing tertiary homoallylic alcohols with excellent yields (up to 98%) and enantioselectivities (up to 98% ee ). Notably, this catalytic system can be recycled up to seven cycles.

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