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Supported Sulfonic Acid as Green and Efficient Catalyst for Baeyer–Villiger Oxidation with 30% Aqueous Hydrogen Peroxide
Author(s) -
Piscopo Calogero G.,
Loebbecke Stefan,
Maggi Raimondo,
Sartori Giovanni
Publication year - 2010
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201000076
Subject(s) - chemistry , hydrogen peroxide , baeyer–villiger oxidation , catalysis , aqueous solution , sulfonic acid , solvent , organic chemistry , green chemistry , stoichiometry , reaction mechanism
Silica‐supported propylsulfonic acid is a very good heterogeneous catalyst for the Baeyer–Villiger oxidation of cyclic ketones to lactones with stoichiometric 30% aqueous hydrogen peroxide in 1,1,1,3,3,3‐hexafluoro‐2‐propanol as solvent.