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An Efficient and Selective Epoxidation of Olefins with Novel Methyltrioxorhenium/(Fluorous Ponytailed) 2,2′‐Bipyridine Catalysts
Author(s) -
Saladino Raffaele,
Ginnasi Maria Cristina,
Collalto Daniela,
Bernini Roberta,
Crestini Claudia
Publication year - 2010
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201000032
Subject(s) - chemistry , hydrogen peroxide , catalysis , bipyridine , organic chemistry , combinatorial chemistry , crystal structure
Novel complexes between methyltrioxorhenium (MTO) and bis(fluorous‐ponytailed) 2,2′‐bipyridines (bpy‐F n ) were synthesized and used for the oxidation of alkenes with hydrogen peroxide under fluorous catalysis. High conversions and yields of the corresponding epoxides were obtained.