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Palladium‐Catalyzed One‐Pot Conversion of Aldehydes to Amides
Author(s) -
Ali Md Ashif,
Punniyamurthy Tharmalingam
Publication year - 2010
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200900799
Subject(s) - chemistry , palladium , hydroxylamine hydrochloride , catalysis , hydroxylamine , chelation , ligand (biochemistry) , organic chemistry , dimethyl sulfoxide , aqueous solution , hydrochloride , primary (astronomy) , sulfoxide , combinatorial chemistry , biochemistry , physics , receptor , astronomy
The palladium‐catalyzed one‐pot conversion of aldehydes into primary amides in the presence of hydroxylamine hydrochloride in aqueous dimethyl sulfoxide (DMSO) at moderate temperature is described. The process is selective and free from the addition of an external chelating ligand.