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Recyclable Heterogeneous Palladium Catalysts in Pure Water: Sustainable Developments in Suzuki, Heck, Sonogashira and Tsuji–Trost Reactions
Author(s) -
Lamblin Marc,
NassarHardy Luma,
Hierso JeanCyrille,
Fouquet Eric,
Felpin FrançoisXavier
Publication year - 2010
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200900765
Subject(s) - sonogashira coupling , chemistry , palladium , catalysis , heterogeneous catalysis , heck reaction , reusability , organic chemistry , combinatorial chemistry , software , computer science , programming language
This review summarizes the progress made essentially these last ten years on heterogeneous palladium catalysis in pure water. The work covers four important palladium‐catalyzed transformations for carbon‐carbon bond formation: Suzuki, Heck, Sonogashira and Tsuji–Trost reactions. The discussion focuses on the efficiency and reusability of the heterogeneous catalysts as well as on the experimental conditions from a sustainable chemistry point of view. The review is introduced by a discussion on mechanistic aspects inherent to heterogeneous catalysis.