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Synthesis of Sulfoximines and Sulfilimines with Aryl and Pyrazolylmethyl Substituents
Author(s) -
Mancheño Olga García,
Dallimore Jonathan,
Plant Andrew,
Bolm Carsten
Publication year - 2010
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200900729
Subject(s) - chemistry , aryl , sulfide , nitrogen , metal , combinatorial chemistry , organic chemistry , medicinal chemistry , alkyl
Sulfoximines bearing pyrazolylmethyl and aryl substituents, which are relevant to the crop protection industry, and their corresponding sulfilimine intermediates, have been prepared from sulfide precursors by either iron‐catalyzed nitrogen transfer reactions or metal‐free imination procedures. Whereas the former approach leads to N ‐nosyl‐substituted products, the latter affords N ‐cyano derivatives.