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Kinetic Resolution of P‐Chirogenic Compounds by Palladium‐Catalyzed Alcoholysis of Vinyl Ethers
Author(s) -
Itoh Hisashi,
Yamamoto Eiji,
Masaoka Shigeyuki,
Sakai Ken,
Tokunaga Makoto
Publication year - 2009
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200900304
Subject(s) - chemistry , kinetic resolution , palladium , catalysis , aryl , organic chemistry , diamine , polymer chemistry , enantioselective synthesis , alkyl
The palladium‐catalyzed asymmetric alcoholysis of vinyl ethers of P‐chirogenic compounds has been achieved. The kinetic resolution of aryl tert ‐butyl(2‐vinyloxyaryl)phosphinates was catalyzed by palladium/chiral diamine complexes with high selectivities ( k rel : 12–196).
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