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Use of Commercially Available Ruthenium Fischer‐Type Carbenes for Ring‐Closing Metathesis Reactions: Scope and Limitations of an in situ Activation Procedure
Author(s) -
Wallace Debra J.
Publication year - 2009
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200900301
Subject(s) - ruthenium , enyne metathesis , chemistry , ring closing metathesis , salt metathesis reaction , metathesis , catalysis , diene , ring (chemistry) , combinatorial chemistry , organic chemistry , polymer , natural rubber , polymerization
An evaluation of two commercially available Fischer‐type ruthenium carbenes in a range of ring‐closing diene and enyne metathesis reactions has been carried out. A method to activate such catalysts for ring‐closing reactions is presented.