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Versatile Supramolecular Copper(II) Complexes for Henry and Aza‐Henry Reactions
Author(s) -
Zhang Guoqi,
Yashima Eiji,
Woggon WolfD.
Publication year - 2009
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200900069
Subject(s) - chemistry , supramolecular chemistry , copper , yield (engineering) , nitroaldol reaction , metal , combinatorial chemistry , organic chemistry , ethanol , organic base , catalysis , polymer chemistry , enantioselective synthesis , molecule , materials science , metallurgy
Chiral supramolecular metal‐organic frameworks assembled from copper complexes catalyse Henry and aza‐Henry reactions of aromatic and aliphatic aldehydes and N ‐protected aromatic imines in high yield and good to excellent enantioselectivity. Reactions can be performed in the absence of base in ethanol or water.