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Cover Picture: (Adv. Synth. Catal. 4/2008)
Publication year - 2008
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200890011
Subject(s) - chemistry , cover (algebra) , lewis acids and bases , aldol reaction , frustrated lewis pair , catalysis , lewis acid catalysis , scandium , enol , silylation , stereochemistry , medicinal chemistry , organic chemistry , mechanical engineering , engineering
The cover picture, provided by Shū Kobayashi, shows an example of chiral Lewis acid catalysis based on Lewis acid–surfactant combined catalysts (LASCs). Chiral hydrophobic environments made up of scandium(III) dodecyl sulfate and a chiral bipyridine ligand catalyze the asymmetric aldol‐type reactions of silyl enol ethers in water as the sole solvent.