A Highly Efficient, Metal‐Free and Convenient Diarylallyl Ether/Thioether Formation  via  Oxidative C‐H Activation | Zendy

Li Yan | Zendy; Bao Weiliang | Zendy

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A Highly Efficient, Metal‐Free and Convenient Diarylallyl Ether/Thioether Formation via Oxidative C‐H Activation

Author(s) -

Li Yan,

Bao Weiliang

Publication year - 2009

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200800810

Subject(s) - thioether , chemistry , ether , oxidative phosphorylation , oxidative coupling of methane , metal , organic chemistry , polymer chemistry , medicinal chemistry , combinatorial chemistry , catalysis , biochemistry

A metal free highly efficient and concise oxidative‐coupling ether formation between 1,3‐diarylallylic sp 3 C‐H and aliphatic alcohols promoted by 2,3‐dichloro‐5,6‐dicyanoquinone (DDQ) is reported. This system is also applied to form CS bonds from 1,3‐diarylpropylene and thiols/thiophenols. The corresponding diarylallyl ethers/thioethers are obtained in good yields.

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