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Increasing the Scope of Palladium‐Catalyzed Cyanations of Aryl Chlorides
Author(s) -
Schareina Thomas,
Jackstell Ralf,
Schulz Thomas,
Zapf Alexander,
Cotté Alain,
Gotta Matthias,
Beller Matthias
Publication year - 2009
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200800733
Subject(s) - chemistry , cyanation , palladium , aryl , potassium ferrocyanide , catalysis , scope (computer science) , substrate (aquarium) , combinatorial chemistry , ferrocyanide , organic chemistry , alkyl , oceanography , electrode , computer science , programming language , geology
An improved protocol for the palladium‐catalyzed cyanation of electron‐rich aryl chlorides with potassium ferrocyanide {K 4 [Fe(CN) 6 ]} is presented. Compared to previous procedures the substrate scope is significantly broadened.