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An Unusual Peroxide‐Mediated Amination of Cycloalkanes with Nitroarenes
Author(s) -
Deng Guojun,
Chen Wenwen,
Li ChaoJun
Publication year - 2009
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200800689
Subject(s) - chemistry , amination , peroxide , organic chemistry , aqueous solution , combinatorial chemistry , catalysis
A direct amination of simple cycloalkanes with nitroarenes mediated by peroxides has been discovered. Various secondary arylamines were obtained efficiently from cycloalkanes. The reaction tolerates a wide range of functionalities as well as aqueous conditions. No metal was required for this novel amination reaction.