Iodine‐Catalyzed Suzuki–Miyaura Coupling Performed in Air | Zendy

Mao Jincheng | Zendy; Hua Qiongqiong | Zendy; Xie Guanlei | Zendy; Guo Jun | Zendy; Yao Zhigang | Zendy; Shi Daqing | Zendy; Ji Shunjun | Zendy

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Iodine‐Catalyzed Suzuki–Miyaura Coupling Performed in Air

Author(s) -

Mao Jincheng,

Hua Qiongqiong,

Xie Guanlei,

Guo Jun,

Yao Zhigang,

Shi Daqing,

Ji Shunjun

Publication year - 2009

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200800624

Subject(s) - chemistry , phenylboronic acid , iodine , catalysis , polyethylene glycol , potassium carbonate , coupling (piping) , suzuki reaction , organic chemistry , palladium , mechanical engineering , engineering

uzuki‐type coupling reactions can be performed directly in air using a catalytic system composed of iodine, potassium carbonate, and polyethylene glycol 400 (I 2 /K 2 CO 3 /PEG‐400). Iodine was found to be an effective additive for accelerating these couplings. The methodology is also suitable for the coupling of ( E )‐ β ‐bromostyene with phenylboronic acid, with retention of the double bond geometry.

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