Ligand‐Accelerated Asymmetric [1,2]‐Stevens Rearrangment of Sulfur Ylides  via  Decomposition of Diazomalonates Catalyzed by Chiral Bisoxazoline/Copper Complex | Zendy

Qu JianPing | Zendy; Xu ZhengHu | Zendy; Zhou Jian | Zendy; Cao ChunLi | Zendy; Sun XiuLi | Zendy; Dai LiXin | Zendy; Tang Yong | Zendy

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Ligand‐Accelerated Asymmetric [1,2]‐Stevens Rearrangment of Sulfur Ylides via Decomposition of Diazomalonates Catalyzed by Chiral Bisoxazoline/Copper Complex

Author(s) -

Qu JianPing,

Xu ZhengHu,

Zhou Jian,

Cao ChunLi,

Sun XiuLi,

Dai LiXin,

Tang Yong

Publication year - 2009

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200800536

Subject(s) - chemistry , copper , catalysis , ligand (biochemistry) , trifluoromethanesulfonate , decomposition , sulfur , enantioselective synthesis , organic chemistry , polymer chemistry , medicinal chemistry , receptor , biochemistry

The first example of catalytic asymmetric [1,2]‐Stevens rearrangement reaction of 1,3‐oxathiolanes with diazomalonates has been developed and up to 90% ee is achieved by the bisoxazoline 4e /copper(II) triflate [Cu(OTf) 2 ] complex.

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