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Palladium‐Catalyzed Synthesis of Selectively Substituted Phenanthridine Derivatives
Author(s) -
Della Ca' Nicola,
Motti Elena,
Catellani Marta
Publication year - 2008
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200800512
Subject(s) - phenanthridine , chemistry , palladium , catalysis , norbornene , aryl , alkylation , combinatorial chemistry , organic chemistry , polymerization , alkyl , polymer
Selectively substituted phenanthridine derivatives are obtained by a facile reaction of o ‐alkylated aryl iodides, o ‐bromoarenesulfonylanilines and activated olefins in the presence of palladium and norbornene as catalysts. The reaction takes place under mild conditions to give the products in satisfactory yields using readily available starting materials.