A Direct Palladium‐Catalyzed Route to Selectively Substituted Carbazoles through Sequential CC and CN Bond Formation: Synthesis of Carbazomycin A | Zendy

Ca' Nicola Della | Zendy; Sassi Giovanni | Zendy; Catellani Marta | Zendy

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A Direct Palladium‐Catalyzed Route to Selectively Substituted Carbazoles through Sequential CC and CN Bond Formation: Synthesis of Carbazomycin A

Author(s) -

Ca' Nicola Della,

Sassi Giovanni,

Catellani Marta

Publication year - 2008

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200800421

Subject(s) - chemistry , palladium , catalysis , norbornene , combinatorial chemistry , organic chemistry , copolymer , polymer

The present paper offers a synthetically simple one‐pot procedure for the catalytic preparation of the biologically interesting class of carbazoles. The new procedure is based on the combined catalysis of palladium and norbornene starting from o ‐substituted iodoarenes and N ‐sulfonylated or N ‐acetylated o ‐bromoanilines. A well‐known member of this class, carbazomycin A, has been successfully prepared.

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