Premium
Glycerol as An Efficient Promoting Medium for Organic Reactions
Author(s) -
Gu Yanlong,
Barrault Joël,
Jérôme François
Publication year - 2008
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200800328
Subject(s) - glycerol , chemistry , solvent , biodiesel , reaction rate , organic chemistry , organic solvent , catalysis , chemical engineering , engineering
Abstract Whereas the beneficial effect of water on reaction rate is decreased with an increase of the reactant′s hydrophobicity, we report here that the use of glycerol as solvent was able to considerably accelerate the reaction rate of an organic reaction even starting from more hydrophobic substrates than those usually used on water. Moreover, the possibility of directly using crude glycerol generated by the biodiesel industry economically and environmentally improves the interest of using glycerol as solvent.