Efficient Synthesis of Substituted Selenophenes Based on the First Palladium(0)‐Catalyzed Cross‐Coupling Reactions of Tetrabromoselenophene | Zendy

Tùng Đǎng Thanh | Zendy; Villinger Alexander | Zendy; Langer Peter | Zendy

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Efficient Synthesis of Substituted Selenophenes Based on the First Palladium(0)‐Catalyzed Cross‐Coupling Reactions of Tetrabromoselenophene

Author(s) -

Tùng Đǎng Thanh,

Villinger Alexander,

Langer Peter

Publication year - 2008

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200800316

Subject(s) - sonogashira coupling , chemistry , regioselectivity , palladium , coupling reaction , aryl , combinatorial chemistry , catalysis , ligand (biochemistry) , suzuki reaction , tetra , organic chemistry , medicinal chemistry , biochemistry , alkyl , receptor

Regioselective Suzuki cross‐coupling reactions of tetrabromoselenophene allow a convenient synthesis of aryl‐substituted selenophenes. High yields were obtained using a novel biaryl‐monophosphine ligand. The first tetra(1‐alkynyl)selenophene was prepared in one step by a Sonogashira reaction of tetrabromoselenophene.

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