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Organocatalytic Enantioselective Hydrophosphonylation of Sulfonylimines having a Heteroarenesulfonyl Group as a Novel Stereocontroller
Author(s) -
Nakamura Shuichi,
Nakashima Hiroki,
Yamamura Akiko,
Shibata Norio,
Toru Takeshi
Publication year - 2008
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200800134
Subject(s) - enantioselective synthesis , chemistry , cinchona , organocatalysis , enantiomer , group (periodic table) , organic chemistry , catalysis
Organocatalytic enantioselective hydrophosphonylation of imines having the a heteroarenesulfonyl group afforded the respective products with high enantioselectivity. Both enantiomers of α‐amino phosphonates were obtained by using different Cinchona alkaloids with up to 98% ee .