Enantioselective Organocatalytic Epoxidation Driven by Electrochemically Generated Percarbonate and Persulfate | Zendy

Page Philip C. Bulman | Zendy; Marken Frank | Zendy; Williamson Craig | Zendy; Chan Yohan | Zendy; Buckley Benjamin R. | Zendy; Bethell Donald | Zendy

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Enantioselective Organocatalytic Epoxidation Driven by Electrochemically Generated Percarbonate and Persulfate

Author(s) -

Page Philip C. Bulman,

Marken Frank,

Williamson Craig,

Chan Yohan,

Buckley Benjamin R.,

Bethell Donald

Publication year - 2008

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200800064

Subject(s) - iminium , chemistry , persulfate , salt (chemistry) , enantioselective synthesis , catalysis , stoichiometry , organic chemistry , electrochemistry , ammonium persulfate , organocatalysis , inorganic chemistry , combinatorial chemistry , electrode , polymer , polymerization

An organocatalytic asymmetric epoxidation reaction using iminium salt catalysts is described, in which the stoichiometric persulfate oxidant is generated electrochemically. This system offers comparable ee s to the use of commercially available persulfate. Electrochemically generated percarbonate ion is also a successful and novel oxidant system for use with iminium salts.

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