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Mechanistic Inferences Derived from Competitive Catalytic Reactions: Pd(binap)‐Catalyzed Amination of Aryl Halides
Author(s) -
Ferretti Antonio C.,
Mathew Jinu S.,
Ashworth Ian,
Purdy Malcolm,
Brennan Colin,
Blackmond Donna G.
Publication year - 2008
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200800006
Subject(s) - chemistry , binap , amination , halide , catalysis , aryl , competition (biology) , aryl halide , combinatorial chemistry , organic chemistry , palladium , enantioselective synthesis , ecology , alkyl , biology
Healthy competition: The Pd(binap)‐catalyzed amination of aryl halides demonstrates how the results from competitive reactions can be strikingly different from those obtained from study of the separate reactions. We show how the competitive network provides mechanistic information not accessible from study of the reactions separately.