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Catalytic Dehydrogenation of o ‐Alkylated or o ‐Alkoxylated Iodoarenes with Concomitant Hydrogenolysis
Author(s) -
Motti Elena,
Catellani Marta
Publication year - 2008
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200700562
Subject(s) - chemistry , dehydrogenation , hydrogenolysis , palladium , catalysis , alkylation , medicinal chemistry , organic chemistry
Palladium‐catalyzed dehydrogenation of suitable chains bonded to an ortho position of an iodoarene has been achieved by two methods both involving oxidative addition of the iodoarene to palladium(0) and palladacycle formation under mild conditions.