Premium
Cyclization of Allenyne‐1,6‐diols Catalyzed by Gold and Silver Salts: An Efficient Selective Synthesis of Dihydrofuran and Furan Derivatives
Author(s) -
Kim Sundae,
Lee Phil Ho
Publication year - 2008
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200700471
Subject(s) - chemistry , furan , chemoselectivity , catalysis , organic chemistry , combinatorial chemistry , silver salts , medicinal chemistry
Treatment of allenyne‐1,6‐diols with gold and silver catalysts selectively produced 2,5‐dihydrofuran and furan derivatives, respectively, in good to excellent yields through the selective activation and differentiation of the double and triple bonds in allenyne‐1,6‐diols. It is noteworthy that the chemoselectivity is clearly switched by simply changing the metal from gold to silver.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom