Catalytic Hydrogenation of α‐Iminophosphonates as a Method for the Synthesis of Racemic and Optically Active α‐Aminophosphonates | Zendy

Goulioukitaliya S. | Zendy; Bondarenko Grigorii N. | Zendy; Lyubimov Sergey E. | Zendy; Davankov Vadim A. | Zendy; Gavrilov Konstantin N. | Zendy; Beletskaya Irina P. | Zendy

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Catalytic Hydrogenation of α‐Iminophosphonates as a Method for the Synthesis of Racemic and Optically Active α‐Aminophosphonates

Author(s) -

Goulioukitaliya S.,

Bondarenko Grigorii N.,

Lyubimov Sergey E.,

Davankov Vadim A.,

Gavrilov Konstantin N.,

Beletskaya Irina P.

Publication year - 2008

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200700466

Subject(s) - chemistry , optically active , enantioselective synthesis , catalysis , binap , rhodium , asymmetric hydrogenation , noyori asymmetric hydrogenation , ligand (biochemistry) , chiral ligand , organic chemistry , combinatorial chemistry , hydrogen , catalytic hydrogenation , biochemistry , receptor

It was shown that the catalytic hydrogenation of α‐iminophosphonates by molecular hydrogen can serve as a convenient method for the synthesis of racemic and optically active α‐aminophosphonates. Up to 94% ee was achieved in the rhodium‐catalyzed enantioselective hydrogenation using chiral ligand ( R )‐BINAP.

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