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Tandem Gold(III)‐Catalyzed Amination‐Intramolecular Hydroamination Reactions of 1‐En‐4‐yn‐3‐ols with Sulfonamides: Efficient Approach to Highly Substituted Pyrroles
Author(s) -
Shu XingZhong,
Liu XueYuan,
Xiao HuiQuan,
Ji KeGong,
Guo LiNa,
Liang YongMin
Publication year - 2008
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200700452
Subject(s) - hydroamination , amination , chemistry , intramolecular force , tandem , catalysis , combinatorial chemistry , organic chemistry , materials science , composite material
A simple, convenient and efficient synthetic approach to highly substituted pyrroles has been developed by utilizing a gold(III)‐catalyzed tandem amination‐intramolecular hydroamination reaction. The first examples of gold‐catalyzed, selective amination of 1‐en‐4‐yn‐3‐ols have also been disclosed.
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