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Silver‐Catalyzed Rearrangement of Propargylic Sulfinates to Allenic Sulfones
Author(s) -
Harmata Michael,
Huang Chaofeng
Publication year - 2008
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200700447
Subject(s) - chemistry , yield (engineering) , catalysis , organic chemistry , silver salts , medicinal chemistry , combinatorial chemistry , metallurgy , materials science
Treatment of propargylic sulfinate esters with 2 mol % of silver hexafluoroantimonate results in the rapid formation of allenic sulfones in essentially quantitative yield.