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Palladium‐Catalyzed/Lewis Acid‐Promoted Alkene Dimerization and Cross‐Coupling with Alcohols via CH Bond Activation
Author(s) -
Jiang YiJun,
Tu YongQiang,
Zhang En,
Zhang ShuYu,
Cao Ke,
Shi Lei
Publication year - 2008
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200700439
Subject(s) - chemistry , alkene , palladium , catalysis , lewis acids and bases , medicinal chemistry , alcohol , photochemistry , polymer chemistry , stereochemistry , organic chemistry
The cross‐couplings of alcohols to alkenes with the palladium/Lewis acid system are reported. This reaction occurs in a successive alkene dimerization, direct CH activation of alcohol and sp 3 sp 3 bond forming sequence via an interesting domino process.