Chiral Bicyclic Guanidine as a Versatile Brønsted Base Catalyst for the Enantioselective Michael Reactions of Dithiomalonates and β‐Keto Thioesters | Zendy

Ye Weiping | Zendy; Jiang Zhiyong | Zendy; Zhao Yujun | Zendy; Goh Serena Li Min | Zendy; Leow Dasheng | Zendy; Soh YingTeck | Zendy; Tan ChoonHong | Zendy

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Chiral Bicyclic Guanidine as a Versatile Brønsted Base Catalyst for the Enantioselective Michael Reactions of Dithiomalonates and β‐Keto Thioesters

Author(s) -

Ye Weiping,

Jiang Zhiyong,

Zhao Yujun,

Goh Serena Li Min,

Leow Dasheng,

Soh YingTeck,

Tan ChoonHong

Publication year - 2007

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200700326

Subject(s) - enantioselective synthesis , chemistry , guanidine , bicyclic molecule , michael reaction , catalysis , brønsted–lowry acid–base theory , organocatalysis , base (topology) , organic chemistry , combinatorial chemistry , mathematical analysis , mathematics

A chiral bicyclic guanidine was developed as a versatile Brønsted base catalyst for the enantioselective Michael reactions of dithiomalonates and β‐keto thioesters using a range of acceptors including maleimides, cyclic enones, furanone and acyclic 1,4‐dicarbonylbutenes.

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