Mechanochemical Aminochlorination of Electron‐Deficient Olefins with Chloramine‐T Promoted by (Diacetoxyiodo)benzene | Zendy

Wang GuanWu | Zendy; Wu XueLiang | Zendy

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Mechanochemical Aminochlorination of Electron‐Deficient Olefins with Chloramine‐T Promoted by (Diacetoxyiodo)benzene

Author(s) -

Wang GuanWu,

Wu XueLiang

Publication year - 2007

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200700020

Subject(s) - chemistry , vicinal , benzene , chloramine , stereoselectivity , chlorine , medicinal chemistry , chloramine t , solvent , organic chemistry , catalysis

A direct and convenient procedure for the solvent‐free mechanochemical aminochlorination of electron‐deficient olefins promoted by (diacetoxyiodo)benzene [PhI(OAc) 2 ] was described using commercially available and cheap chloramine‐T as a nitrogen and chlorine source. The vicinal chloramine derivatives were obtained in high regio‐ and stereoselectivity with good yields. PhI(OAc) 2 was superior to metal salts for the aminochlorination of electron‐deficient olefins.

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