Waste‐Free Electrochemical Oxidation of Alcohols in Water | Zendy

Palmisano Giovanni | Zendy; Ciriminna Rosaria | Zendy; Pagliaro Mario | Zendy

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Waste‐Free Electrochemical Oxidation of Alcohols in Water

Author(s) -

Palmisano Giovanni,

Ciriminna Rosaria,

Pagliaro Mario

Publication year - 2006

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200606199

Subject(s) - chemistry , acetonitrile , alcohol oxidation , electrochemistry , environmentally friendly , catalysis , nitroxyl , bicarbonate , electrode , solvent , inorganic chemistry , organic chemistry , chemical engineering , ecology , engineering , biology

We describe a new sol‐gel molecular electrode made of a thin layer of organosilica doped with the nitroxyl radical TEMPO (2,2,6,6‐tetramethylpiperidine‐1‐oxyl) electrodeposited on the surface of an ITO‐coated glass and its employment as a selective and versatile oxidation catalyst in the electrochemical conversion of different alcohols to carbonyl compounds. Environmentally friendly water or a water/acetonitrile mixture buffered with bicarbonate is used as solvent. The electrode is highly stable and it can be reused for a prolonged period of time allowing easy separation from the products.

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