Hydrophilic CNC‐Pincer Palladium Complexes: A Source for Highly Efficient, Recyclable Homogeneous Catalysts in Suzuki–Miyaura Cross‐Coupling | Zendy

Churruca Fátima | Zendy; SanMartin Raul | Zendy; Inés Blanca | Zendy; Tellitu Imanol | Zendy; Domínguez Esther | Zendy

Premium

Hydrophilic CNC‐Pincer Palladium Complexes: A Source for Highly Efficient, Recyclable Homogeneous Catalysts in Suzuki–Miyaura Cross‐Coupling

Author(s) -

Churruca Fátima,

SanMartin Raul,

Inés Blanca,

Tellitu Imanol,

Domínguez Esther

Publication year - 2006

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200606173

Subject(s) - pincer movement , chemistry , palladium , homogeneous , catalysis , coupling (piping) , homogeneous catalysis , suzuki reaction , combinatorial chemistry , organic chemistry , polymer chemistry , metallurgy , physics , materials science , thermodynamics

The Suzuki biaryl coupling of a range of electronically dissimilar arylboronic acids and aryl bromides is performed in neat water with excellent to quantitative yields by means of a new CNC‐pincer palladium catalyst that is soluble in water due to its para ‐carboxy group. Extremely high turnover numbers and frequencies combined with a remarkable robustness allow an effective catalyst reuse in sustainable conditions.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research