Water‐Soluble Triphenylphosphane‐3,3′,3′′‐tricarboxylate ( m ‐TPPTC) Ligand and Methylated Cyclodextrins: A New Combination for Biphasic Rhodium‐Catalyzed Hydroformylation of Higher Olefins | Zendy

Tilloy Sébastien | Zendy; Genin Emilie | Zendy; Hapiot Frédéric | Zendy; Landy David | Zendy; Fourmentin Sophie | Zendy; Genêt JeanPierre | Zendy; Michelet Véronique | Zendy; Monflier Eric | Zendy

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Water‐Soluble Triphenylphosphane‐3,3′,3′′‐tricarboxylate ( m ‐TPPTC) Ligand and Methylated Cyclodextrins: A New Combination for Biphasic Rhodium‐Catalyzed Hydroformylation of Higher Olefins

Author(s) -

Tilloy Sébastien,

Genin Emilie,

Hapiot Frédéric,

Landy David,

Fourmentin Sophie,

Genêt JeanPierre,

Michelet Véronique,

Monflier Eric

Publication year - 2006

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200606160

Subject(s) - hydroformylation , chemistry , tppts , rhodium , catalysis , aqueous solution , ligand (biochemistry) , tris , salt (chemistry) , cyclodextrin , organic chemistry , medicinal chemistry , biochemistry , receptor

The methylated cyclodextrins/ m ‐TPPTC [tris( m ‐carboxyphenyl)phosphane trilithium salt] couples proved to be more efficient than the well‐known methylated cyclodextrins/TPPTS [tris( m ‐sulfonatophenyl)phosphane trisodium salt] systems in terms of activities and selectivities to perform the Rh‐catalyzed hydroformylation of higher olefins in an aqueous‐organic system. The interactions cyclodextrins/ m ‐TPPTC have been fully studied by NMR spectroscopy.

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