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Water‐Soluble Triphenylphosphane‐3,3′,3′′‐tricarboxylate ( m ‐TPPTC) Ligand and Methylated Cyclodextrins: A New Combination for Biphasic Rhodium‐Catalyzed Hydroformylation of Higher Olefins
Author(s) -
Tilloy Sébastien,
Genin Emilie,
Hapiot Frédéric,
Landy David,
Fourmentin Sophie,
Genêt JeanPierre,
Michelet Véronique,
Monflier Eric
Publication year - 2006
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200606160
Subject(s) - hydroformylation , chemistry , tppts , rhodium , catalysis , aqueous solution , ligand (biochemistry) , tris , salt (chemistry) , cyclodextrin , organic chemistry , medicinal chemistry , biochemistry , receptor
The methylated cyclodextrins/ m ‐TPPTC [tris( m ‐carboxyphenyl)phosphane trilithium salt] couples proved to be more efficient than the well‐known methylated cyclodextrins/TPPTS [tris( m ‐sulfonatophenyl)phosphane trisodium salt] systems in terms of activities and selectivities to perform the Rh‐catalyzed hydroformylation of higher olefins in an aqueous‐organic system. The interactions cyclodextrins/ m ‐TPPTC have been fully studied by NMR spectroscopy.