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Synthesis of Novel Bisphosphine‐Containing Polymers and Their Applications as Bidentate Ligands for Nickel(0)‐Catalyzed Cross‐Coupling Reactions
Author(s) -
Lu Yong,
Plocher Elizabeth,
Hu QiaoSheng
Publication year - 2006
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200606002
Subject(s) - chemistry , aryl , catalysis , denticity , ferrocene , combinatorial chemistry , reagent , nickel , coupling reaction , polymer chemistry , transition metal , polymer , organic chemistry , metal , alkyl , electrode , electrochemistry
The efficient synthesis of two examples of a new type of ferrocene‐based bisphosphine‐containing polymers and their application as bidentate ligands for Ni(0)‐catalyzed cross‐coupling reactions of aryl chlorides with arylboronic acids, and aryl fluorides with Grignard reagents are described. Our study may provide a new family of bisphosphine‐containing polymers that are readily accessible and potentially useful in transition metal catalysis.