Solvent‐ and Metal‐Free Ketonization of Fatty Acid Methyl Esters and Triacylglycerols with Nitrous Oxide | Zendy

Hermans Ive | Zendy; Janssen Kris | Zendy; Moens Bart | Zendy; Philippaerts An | Zendy; Van Berlo Boris | Zendy; Peeters Jozef | Zendy; Jacobs Pierre A. | Zendy; Sels Bert F. | Zendy

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Solvent‐ and Metal‐Free Ketonization of Fatty Acid Methyl Esters and Triacylglycerols with Nitrous Oxide

Author(s) -

Hermans Ive,

Janssen Kris,

Moens Bart,

Philippaerts An,

Van Berlo Boris,

Peeters Jozef,

Jacobs Pierre A.,

Sels Bert F.

Publication year - 2007

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200600645

Subject(s) - chemistry , catalysis , organic chemistry , nitrous oxide , metal , solvent , oxide , green chemistry , reaction mechanism

Herein we report a new, one‐step procedure for the metal‐free ketonization of unsaturated fatty acid methyl esters and triacylglycerol mixtures with nitrous oxide (N 2 O). The conversion of various substrates can be tuned by parameters such as temperature, reaction time and N 2 O partial pressure. This ketonization chemistry offers various advantages over the classic Wacker catalytic process and a state‐of‐the‐art two‐step procedure via intermediate epoxides.

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