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Josiphos Ligands with an Imidazolium Tag and their Application for the Enantioselective Hydrogenation in Ionic Liquids
Author(s) -
Feng Xiangdong,
Pugin Benoît,
Küsters Ernst,
Sedelmeier Gottfried,
Blaser HansUlrich
Publication year - 2007
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200600636
Subject(s) - ionic liquid , enantioselective synthesis , chemistry , moiety , reusability , rhodium , catalysis , solvent , asymmetric hydrogenation , organic chemistry , combinatorial chemistry , software , computer science , programming language
Josiphos ligands bearing an imidazolium moiety show high efficiency and reusability for the rhodium‐catalyzed enantioselective hydrogenation of methyl acetamidoacrylate (MAA) and dimethyl itaconate (DMI) in biphasic co‐solvent/ionic liquid combinations.
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