Synthesis of Enantiopure ( S , R , S )‐ and ( R , S , R )‐1,4,5,8,9,16‐Hexahydroxytetraphenylenes | Zendy

Wu AnHui | Zendy; Hau ChunKit | Zendy; Wong Henry N. C. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Synthesis of Enantiopure ( S , R , S )‐ and ( R , S , R )‐1,4,5,8,9,16‐Hexahydroxytetraphenylenes

Author(s) -

Wu AnHui,

Hau ChunKit,

Wong Henry N. C.

Publication year - 2007

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200600499

Subject(s) - enantiopure drug , chemistry , iodobenzene , stereochemistry , medicinal chemistry , organic chemistry , enantioselective synthesis , catalysis

1,4,5,8,9,16‐Hexahydroxytetraphenylene ( 5 ) was synthesized by an iodobenzene diacetate‐mediated phenolic oxidation. Enantiopure forms of 1,4,5,8,9,16‐hexahydroxytetraphenylenes [( S , R , S )‐ 5 and ( R , S , R )] were successfully synthesized either by using ( S , S )‐and ( R , R )‐1,8,9,16‐tetramethoxytetraphenylenes [( S , S )‐ 7 and ( R , R )‐ 7 ] as starting materials or by direct resolution of 1,4,5,8,9,16‐hexahydroxytetraphenylene ( 5 ).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research