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Diarylmethanols by Catalyzed Asymmetric Aryl Transfer Reactions onto Aldehydes Using Boronic Acids as Aryl Source
Author(s) -
Schmidt Frank,
Rudolph Jens,
Bolm Carsten
Publication year - 2007
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200600390
Subject(s) - chemistry , aryl , ferrocene , catalysis , combinatorial chemistry , optically active , organic chemistry , enantioselective synthesis , alkyl , electrode , electrochemistry
Using a planar‐chiral ferrocene as catalyst and combinations of functionalized aldehydes and substituted arylboronic acids as starting materials, asymmetric aryl transfer reactions give access to structurally diverse, optically active diarylmethanols in high yields and enantioselectivities.